Explosophore

Template:Short description Explosophores are functional groups in organic chemistry that give organic compounds explosive properties.

History

The term was first coined by Russian chemist V. Pletz in 1935 and originally mistranslated in some articles as plosophore. Also of note is an auxoexplose concept (similar to chromophore and auxochrome concept), which is a group that modifies the explosive capability of the molecule. The term explosophore has been used more frequently after its use in books such as Organic Chemistry of Explosives by J. Agrawal and R. Hodgson (2007)'.

Properties

Nitrogen-containing explosophores (groups I, II and III below) are particularly strong because in addition to providing oxygen they react to form molecular nitrogen, which is a very stable molecule, and thus the overall reaction is strongly exothermic. The gas formed also expands, causing the shock wave which is observed.

Classification

Pletz grouped the explosophores into eight distinct categories.

I. −NO₂, −ON=O, −ONO₂

These represent:

• the nitro group, a nitrogen atom bound to two oxygen atoms as well as an organic molecule (e.g. TNT, RDX)
• the nitrate ion, a nitrogen atom bound to three oxygen atoms, (e.g. nitroglycerin, ANFO)
• the nitrite ion, a nitrogen atom bound to two oxygen atoms

Most commercially used explosives include the nitrate ion or the nitro group.

II. −N=N−, −N⁻=N⁺=N⁻−

The azo and azide groups respectively, connected to organic/inorganic compounds (e.g. silver azide AgN₃, lead azide Pb(N₃)₂, ammonium azide NH₄N₃)

III. −R_nNX_m

The halogenated nitrogen group X:halogen (e.g. nitrogen triiodide NI₃ and nitrogen trichloride NCl₃)

IV. −C=N−O−

The fulminate group (e.g. fulminic acid HONC and mercury fulminate Hg(ONC)₂)

V. −OClO₂, −OClO₃

The chlorate and perchlorate groups respectively, connected to organics/inorganics (e.g. potassium chlorate KClO₃, fluorine perchlorate FOClO₃)

VI. −O−O−, −O₃−

The peroxide and ozonide groups respectively, connected to organics/inorganics (e.g. acetone peroxide, butanone peroxide)

VII. −C≡C⁻ M⁺

The acetylide group with its metal derivatives (e.g. silver acetylide Ag₂C₂, copper acetylide Cu₂C₂)

VIII. A metal atom connected by an unstable bond to the carbon of certain organic radicals

This class contains for instance organic compounds of mercury, thallium, and lead.

Other

Other substances have been characterised as explosophores outside of the eight classes as defined by Pletz.