Ferrocenium tetrafluoroborate
Page Template:Chembox/styles.css has no content.
Template:Chembox AllOtherNamesTemplate:Chembox IndexlistTemplate:Chembox JmolTemplate:Chembox ECHATemplate:Chembox E numberTemplate:Chembox CompToxTemplate:Chembox GHS (set)Template:Chembox SDSTemplate:Chembox Datapage check| Lua error in package.lua at line 80: module 'Module:InfoboxImage/data' not found. | |
| Lua error in package.lua at line 80: module 'Module:InfoboxImage/data' not found. | |
| Lua error in package.lua at line 80: module 'Module:InfoboxImage/data' not found. | |
| IdentifiersTemplate:Chembox parametercheckScript error: No such module "TemplatePar". | |
|---|---|
| Page Template:Plainlist/styles.css has no content. | |
| ChEBI | Page Template:Plainlist/styles.css has no content. |
| ChEMBL | Page Template:Plainlist/styles.css has no content. |
| ChemSpider | Page Template:Plainlist/styles.css has no content. |
| DrugBank | Page Template:Plainlist/styles.css has no content. |
| EC Number | Page Template:Plainlist/styles.css has no content. |
| Page Template:Plainlist/styles.css has no content. | |
| KEGG | Page Template:Plainlist/styles.css has no content. |
PubChem CID
|
Page Template:Plainlist/styles.css has no content. |
| RTECS number | Page Template:Plainlist/styles.css has no content. |
| UNII | Page Template:Plainlist/styles.css has no content. |
| PropertiesScript error: No such module "TemplatePar". | |
| C10H10BFeF4 | |
| Molar mass | 272.84 g/mol |
| Appearance | dark blue powder |
| Melting point | 178 °C (352 °F; 451 K) (decomposes) |
| Solubility in acetonitrile | SolubleLua error in package.lua at line 80: module 'Module:Category handler/data' not found.[citation needed] |
| Hazards[2]Script error: No such module "TemplatePar". | |
| Related compoundsScript error: No such module "TemplatePar". | |
Related compounds
|
Ferrocene |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
Template:Chembox Footer/trackingScript error: No such module "TemplatePar".Template:Short description
Ferrocenium tetrafluoroborate is an organometallic compound with the formula [Fe(C5H5)2]BF4. This salt is composed of the cation [Fe(C5H5)2]+ and the tetrafluoroborate anion (BFScript error: No such module "su".). The related hexafluorophosphate is also a popular reagent with similar properties. The ferrocenium cation is often abbreviated Fc+ or Cp2Fe+. The salt is deep blue in color and paramagnetic.
Ferrocenium salts are one-electron oxidizing agents, and the reduced product, ferrocene, is inert and often readily separated from ionic products. The ferrocene–ferrocenium couple is used as a reference in electrochemistry. The standard potential of ferrocene-ferrocenium is dependent on specific electrochemical conditions.[3]
Preparation
Commercially available, this compound may be prepared by oxidizing ferrocene typically with ferric salts followed by addition of fluoroboric acid.[3] A variety of other oxidants work well also, such as nitrosyl tetrafluoroborate.[4] Many analogous ferrocenium salts are known.[5]
Structure
According to X-ray crystallography, the structures of the metallocene component of FcBF4 and the parent ferrocene are very similar. The Fe-C distances in the cation are 209.5 pm, about 2% longer than the Fe-C distances in ferrocene. [6]
References
Page Template:Reflist/styles.css has no content.
- ^ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Utilities' not found.
- ^ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Utilities' not found.
- ^ a b Lua error in package.lua at line 80: module 'Module:Citation/CS1/Utilities' not found.
- ^ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Utilities' not found.
- ^ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Utilities' not found.
- ^ Lua error in package.lua at line 80: module 'Module:Citation/CS1/Utilities' not found.
Lua error in package.lua at line 80: module 'Module:Navbox/configuration' not found. Template:Tetrafluoroborates
