Ammonium phosphate

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Ammonium phosphate[1]
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Names
IUPAC name
ammonium phosphate
Other names
triammonium phosphate
Identifiers
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3D model (JSmol)
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  • InChI=1S/3H3N.H3O4P/c;;;1-5(2,3)4/h3*1H3;(H3,1,2,3,4) checkY
    Key: ZRIUUUJAJJNDSS-UHFFFAOYSA-N checkY
  • InChI=1/3H3N.H3O4P/c;;;1-5(2,3)4/h3*1H3;(H3,1,2,3,4)
    Key: ZRIUUUJAJJNDSS-UHFFFAOYAA
  • [O-]P([O-])([O-])=O.[NH4+].[NH4+].[NH4+]
Properties
(NH4)3PO4
Molar mass 149.09 g/mol
Appearance White, tetrahedral crystals
58.0 g/100 mL (25 °C)
Solubility Insoluble in acetone[2]
Hazards
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2
0
0
Thermochemistry
−1671.9 kJ/mol
Related compounds
Other cations
Trisodium phosphate
Tripotassium phosphate
Related compounds
Diammonium phosphate
Monoammonium phosphate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Template:Chembox Footer/trackingTemplate:Short description

Ammonium phosphate is the inorganic compound with the formula (NH4)3PO4. It is the ammonium salt of orthophosphoric acid. A related double salt, (NH4)3PO4.(NH4)2HPO4 is also recognized but is impractical to use. Both triammonium salts evolve ammonia. In contrast to the unstable nature of the triammonium salts, the diammonium phosphate (NH4)2HPO4 and monoammonium salt (NH4)H2PO4 are stable materials that are commonly used as fertilizers to provide plants with fixed nitrogen and phosphorus.[3]

Ammonium phosphate is the main ingredient in pink fire retardant. [4]

Preparation of triammonium phosphate

Triammonium phosphate can be prepared in the laboratory by treating 85% phosphoric acid with 30% ammonia solution:[citation needed]

H3PO4 + 3 NH3 → (NH4)3PO4

(NH4)3PO4 is a colorless, crystalline solid. The solid, which has the odor of ammonia, is readily soluble in water. The salt converts to diammonium hydrogen phosphate (NH4)2HPO4.

See also

References

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  1. ^ Page Module:Citation/CS1/styles.css has no content.Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, Florida: CRC Press. pp. 4–42, 5–19. ISBN 978-0-8493-0594-8.
  2. ^ Page Module:Citation/CS1/styles.css has no content.John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99th ed.). CRC Press. pp. 4–41. ISBN 978-1138561632.
  3. ^ Script error: No such module "Template wrapper".
  4. ^ Page Module:Citation/CS1/styles.css has no content.Press • •, Tammy Webber | The Associated (2025-01-14). "What to know about the pink flame retardants are being used for California fires". NBC Los Angeles. Retrieved 2025-01-15.

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