Decene

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Decene
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Names
Preferred IUPAC name
Dec-1-ene
Other names
Alpha Olefin C10; Decylene; α-Decene; 1-decene
Identifiers
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3D model (JSmol)
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UN number 3295, 1993
  • InChI=1S/C10H20/c1-3-5-7-9-10-8-6-4-2/h3H,1,4-10H2,2H3 checkY
    Key: AFFLGGQVNFXPEV-UHFFFAOYSA-N checkY
  • InChI=1/C10H20/c1-3-5-7-9-10-8-6-4-2/h3H,1,4-10H2,2H3
    Key: AFFLGGQVNFXPEV-UHFFFAOYAO
  • CCCCCCCCC=C
Properties
C10H20
Molar mass 140.270 g·mol−1
Density 0.74 g/cm3[1]
Melting point −66.3 °C (−87.3 °F; 206.8 K)[1]
Boiling point 172 °C (342 °F; 445 K)[1]
Hazards
Related compounds
Related Alkenes
Octene
Nonene
Undecene
Dodecene
Related compounds
Decane
Decanol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Decene /dɛkn/ is an organic compound with the chemical formula Page Module:Chem2/styles.css has no content.C10H20. Decene contains a chain of ten carbon atoms with one double bond, making it an alkene. There are many isomers of decene depending on the position and geometry of the double bond. Dec-1-ene is the only isomer of industrial importance. As an alpha olefin, it is used as a comonomer in copolymers and is an intermediate in the production of epoxides, amines, oxo alcohols, synthetic lubricants, synthetic fatty acids and alkylated aromatics.[2]

The industrial processes used in the production of dec-1-ene are oligomerization of ethylene by the Ziegler process or by the cracking of petrochemical waxes.[3]

In ethenolysis, methyl oleate, the methyl ester of oleic acid, converts to 1-decene and methyl 9-decenoate:[4]

CHA3(CHA2)A7CH=CH(CHA2)A7COA2Memethyl oleate+CHA2=CHA2CHA3(CHA2)A7CH=CHA21-decene+MeOA2C(CHA2)A7CH=CHA29-decenoate

Dec-1-ene has been isolated from the leaves and rhizome of the plant Farfugium japonicum and has been detected as the initial product in the microbial degradation of n-decane.

References

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  1. ^ a b c Record in the GESTIS Substance Database of the Institute for Occupational Safety and Health
  2. ^ http://www.ineosoligomers.com/media/files/lao/LAO%20C10%20Data%20Sheet.pdf 1-Decene (Alpha Olefin C10)], ineosoligomers.com
  3. ^ Alfa Olefins Script error: No such module "webarchive"., SIDS Initial Assessment Report
  4. ^ Page Module:Citation/CS1/styles.css has no content.Marinescu, Smaranda C.; Schrock, Richard R.; Müller, Peter; Hoveyda, Amir H. (2009). "Ethenolysis Reactions Catalyzed by Imido Alkylidene Monoaryloxide Monopyrrolide (MAP) Complexes of Molybdenum". J. Am. Chem. Soc. 131 (31): 10840–10841. Bibcode:2009JAChS.13110840M. doi:10.1021/ja904786y. PMID 19618951.

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