Imogolite

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Imogolite
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Imogolite soil (brown) with fragments of transparent imogolite films
General
CategoryPhyllosilicate minerals
FormulaPage Module:Chem2/styles.css has no content.Al2SiO3(OH)4
IMA symbolImo[1]
Strunz classification9.ED.20
Crystal systemTetragonal
Unknown space group
Identification
ColorWhite, blue, green, brown, black
Crystal habitConchoidal to earthy masses of microscopic threadlike particles and bundles of fine tubes, each about 20 Å in diameter
Mohs scale hardness2–3
LusterVitreous, resinous, waxy
DiaphaneityTransparent to translucent
Specific gravity2.7
Optical propertiesIsotropic
Refractive indexn=1.47–1.51
References[2][3][4]

Imogolite is an aluminium silicate clay mineral with the chemical formula Page Module:Chem2/styles.css has no content.Al2SiO3(OH)4. It occurs in soils formed from volcanic ash and was first described in 1962 for an occurrence in Uemura, Kumamoto prefecture, Kyushu Region, Japan.[2] Its name originates from the Japanese word Script error: No such module "lang"., which refers to the brownish yellow soil derived from volcanic ash. It occurs together with allophane, quartz, cristobalite, gibbsite, vermiculite and limonite.[3]

Imogolite consists of a network of nanotubes with an outer diameter of ca. 2 nm and an inner diameter of ca. 1 nm. The tube walls are formed by continuous Page Module:Chem2/styles.css has no content.Al(OH)3 (gibbsite) sheets and orthosilicate anions (Page Module:Chem2/styles.css has no content.O3SiOH groups). Owing to its tubular structure, natural availability, and low toxicity, imogolite has potential applications in polymer composites, fuel gas storage, absorbents, and as a catalyst support in chemical catalysis.[5]

References

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  1. ^ Page Module:Citation/CS1/styles.css has no content.Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ a b Page Module:Citation/CS1/styles.css has no content."Imogolite: Mineral information, data and localities". Mindat.org. Hudson Institute of Mineralogy. Retrieved 27 Jun 2019.
  3. ^ a b Page Module:Citation/CS1/styles.css has no content.Anthony JW, Bideaux RA, Bladh KW, et al., eds. (1995). "Imogolite" (PDF). Handbook of Mineralogy. Vol. II (Silica, Silicates). Chantilly, VA, US: Mineralogical Society of America. ISBN 9780962209710.
  4. ^ Page Module:Citation/CS1/styles.css has no content."Imogolite Mineral Data". Webmineral.com. Retrieved 27 Jun 2019.
  5. ^ Page Module:Citation/CS1/styles.css has no content.Yah WO, Yamamoto K, Jiravanichanun N, et al. (2010). "Imogolite Reinforced Nanocomposites: Multifaceted Green Materials". Materials. 3 (3): 1709–1745. Bibcode:2010Mate....3.1709Y. doi:10.3390/ma3031709. PMC 5445889.

Further reading

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