Metallate
Lua error in package.lua at line 80: module 'Module:Hatnote list' not found. Metallate or metalate is the name given to any complex anion containing a metal ligated to two or more atoms and/or groups of atoms.
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Typically, the metal is one of the transition elements and the ligand is oxygen or another chalcogenide, a cyanide group or a halogen (though others are known).
The chalcogenide metallates are known as oxometallates, thiometallates, selenometallates and tellurometallates; the cyanide metallates are known as cyanometallates; the halogenide metalates are known as halogenometallates.
Oxometallates include permanganate Page Module:Chem2/styles.css has no content.MnO−4, chromate Page Module:Chem2/styles.css has no content.CrO2−4, vanadate Page Module:Chem2/styles.css has no content.VO−3 or Page Module:Chem2/styles.css has no content.VO3−4 and tungstate Page Module:Chem2/styles.css has no content.WO2−4.
Thiometallates include tetrathiovanadate Page Module:Chem2/styles.css has no content.VS3−4, tetrathiomolybdate Page Module:Chem2/styles.css has no content.MoS2−4, tetrathiotungstate Page Module:Chem2/styles.css has no content.WS2−4and similar ions.[1]
Cyanometallates include ferricyanide Page Module:Chem2/styles.css has no content.[Fe(CN)6]3−, ferrocyanide Page Module:Chem2/styles.css has no content.[Fe(CN)6]4− and dicyanoargentate(I) Page Module:Chem2/styles.css has no content.[Ag(CN)2]−.
Halogenometallates include tetrachloroaluminate Page Module:Chem2/styles.css has no content.[AlCl4]−, tetrachloronickelate(II) Page Module:Chem2/styles.css has no content.[NiCl4]2− and hexafluoroplatinate(V) Page Module:Chem2/styles.css has no content.[PtCl6]−.
Others include tetranitratoaluminate Page Module:Chem2/styles.css has no content.[Al(NO3)4]− and tetrahydroxozincate Page Module:Chem2/styles.css has no content.[Zn(OH)4]2−.
Metallate is also used as a verb by bioinorganic chemistry to describe the act of adding metal atoms or ions to a site (synthetic ligand or protein).
See also
References
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- ^ Page Module:Citation/CS1/styles.css has no content.Diemann, E.; Müller, A. (1973). "Schwefel- und Selenverbindungen von Übergangsmetallen mit d0-Konfiguration" [Sulfur and selenium compounds of transition metals with d0 configurations]. Coordination Chemistry Reviews. 10 (1–2): 79–122. doi:10.1016/S0010-8545(00)80232-5.
