Triazane
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| Names | |
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| Systematic IUPAC name
Triazane[1] | |
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3D model (JSmol)
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PubChem CID
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| Properties | |
| Page Module:Chem2/styles.css has no content.N3H5 | |
| Molar mass | 47.061 g·mol−1 |
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Related compounds
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Template:Chembox Footer/trackingTemplate:Short description
Triazane is an inorganic compound with the chemical formula Page Module:Chem2/styles.css has no content.NH2NHNH2 or Page Module:Chem2/styles.css has no content.N3H5.[2] Triazane is the third simplest acyclic azane after ammonia and hydrazine. It can be synthesized from hydrazine but is unstable and cannot be isolated in the free base form, only as salt forms such as triazanium sulfate.[3] Attempts to convert triazanium salts to the free base release only diazene and ammonia.[4] Triazane has been stabilized as a complex ion with zeolitic silver structures.[5] Triazane has also been synthesized in electron-irradiated ammonia ices and detected as a stable gas-phase product after sublimation.[6]
Compounds containing the triazane skeleton
Several compounds containing the triazane skeleton are known, including 1-methyl-1-nitrosohydrazine (Page Module:Chem2/styles.css has no content.NH2−N(CH3)−N=O), produced from the solventless reaction of methylhydrazine (Page Module:Chem2/styles.css has no content.CH3NHNH2) and an alkyl nitrite (R−O−N=O):[7]
- Page Module:Chem2/styles.css has no content.CH3NHNH2 + RONO → NH2N(CH3)NO + ROH
1-Methyl-1-nitrosohydrazine is a colorless solid, sensitive to impact, but not to friction. It melts at 45 °C and decomposes at 121 °C.[7]
References
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- ^ Page Module:Citation/CS1/styles.css has no content."triazane - PubChem Public Chemical Database". The PubChem Project. USA: National Center for Biotechnology Information.
- ^ IUPAC Goldbook
- ^ Page Module:Citation/CS1/styles.css has no content.H. Al Rasheed, Hessa; M. Malebari, Azizah; A. Dahlous, Kholood; El-Faham, Ayman (2020-06-11). "Synthesis and Characterization of New Series of 1,3-5-Triazine Hydrazone Derivatives with Promising Antiproliferative Activity". Molecules. 25 (11): 2708. doi:10.3390/molecules25112708. ISSN 1420-3049. PMC 7321239. PMID 32545272.
- ^ Wiberg, Holleman & Wiberg. Inorganic Chemistry. p 627. Template:ISBN
- ^ Page Module:Citation/CS1/styles.css has no content.Heo, Nam Ho; Kim, Yang; Kim, Jong Jin; Seff, Karl (2016-03-17). "Surprising Intrazeolitic Chemistry of Silver". The Journal of Physical Chemistry C. 120 (10): 5277–5287. doi:10.1021/acs.jpcc.5b11490. ISSN 1932-7447.
- ^ Förstel, Maksyutenko, Jones, Sun, Chen, Chang, & Kaiser. "Detection of the Elusive Triazane Molecule ([N
3H
5]) in the Gas Phase", ChemPhysChem, 2015, 16, 3139. - ^ a b Page Module:Citation/CS1/styles.css has no content.Miró Sabaté, Carles; Delalu, Henri (2012). "Synthesis, Characterization, and Energetic Properties of Nitroso Compounds". Zeitschrift für anorganische und allgemeine Chemie. 638 (2): 336–344. doi:10.1002/zaac.201100446. ISSN 1521-3749.
External links
- 1-methyl-1-nitrosohydrazine, shows structure of 1-methyl-1-nitrosohydrazine
