Triphosphane

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Triphosphane
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Names
Systematic IUPAC name
Triphosphane[2]
Other names
Triphosphine[1]
Identifiers
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3D model (JSmol)
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  • InChI=1S/H5P3/c1-3-2/h3H,1-2H2 N
    Key: ITHPEWAHFNDNIO-UHFFFAOYSA-N N
  • PPP
Properties
Page Module:Chem2/styles.css has no content.P3H5
Molar mass 97.96099 g·mol−1
Appearance Colourless gas
Related compounds
Other anions
triazane
Related Binary phosphanes
phosphane
diphosphane
Related compounds
triazene
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

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Triphosphane (IUPAC systematic name) or triphosphine is an inorganic compound having the chemical formula Page Module:Chem2/styles.css has no content.HP(PH2)2. It can be generated from diphosphine but is highly unstable at room temperature:[3]

Page Module:Chem2/styles.css has no content.2 P2H4 → P3H5 + PH3

Samples have been isolated by gas chromatography. The compound rapidly converts to Page Module:Chem2/styles.css has no content.PH3 and the cyclophosphine cyclo-Page Module:Chem2/styles.css has no content.P5H5.[4]

References

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  1. ^ Page Module:Citation/CS1/styles.css has no content."Triphosphine". NIST Chemistry WebBook. USA: National Institute of Standards and Technology. Retrieved 27 September 2011.
  2. ^ Page Module:Citation/CS1/styles.css has no content."triphosphane (CHEBI:35893)". Chemical Entities of Biological Interest (ChEBI). UK: European Bioinformatics Institute. 7 June 2006. Main. Retrieved 27 September 2011.
  3. ^ Page Module:Citation/CS1/styles.css has no content.Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. doi:10.1016/C2009-0-30414-6. ISBN 978-0-08-037941-8.
  4. ^ Page Module:Citation/CS1/styles.css has no content.Marianne Baudler, Klaus Glinka (1993). "Monocyclic and Polycyclic Phosphines". Chem. Rev. 93: 1623–1667. doi:10.1021/cr00020a010.

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